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Dojindo,ODPA/100/O407,膦酸衍生物同样在金属氧化物上形成SAM
膦酸衍生物用于氧化金属的表面改性，如 Al2O31)、TiO22)、ZrO23)、SiO24)、Mica5)、不锈钢(SS316L)6)、镍钛诺7)、羟基磷灰石8)、AgO9)、ZnO10)、ITO11、12 ). 长期以来，有机硅烷一直被用于在金属氧化物上形成自组装单层 (SAM)。 然而，由于试剂之间的稳定性和聚合性差，在应用中并不总是适用。 另一方面，膦酸衍生物同样在金属氧化物上形成SAM，尽管它们是非常稳定的化合物。 此外，据报道，膦酸衍生物使用形成比有机硅烷更稳定和致密的 SAM。 克劳克等。 人。 和 Sekitani 等。 人。 显示 Al2O3 上的烷基膦酸酯 SAM 比三氯硅烷衍生物 SAM 作为有机晶体管的导体膜更有用13）。